3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(m-tolyl)propanoic acid

Name: 3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(m-tolyl)propanoic acid
Brand: ChemScene
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CAS No. 284492-06-4
Cat. No. CS-0181513
Purity≥98%
MDL No.MFCD02090652

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3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(m-tolyl)propanoic acid|CS-0181513

Structure of 284492-06-4

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General Information

CAS No. 284492-06-4
Cat. No. CS-0181513
Purity ≥98%
MDL No. MFCD02090652
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₅H₂₃NO₄
Molecular Weight 401.45
Synonym(s) N-FMOC-3-AMINO-3-M-TOLYL-PROPIONIC ACID
SMILES O=C(O)CC(NC(OCC1C2=C(C3=C1C=CC=C3)C=CC=C2)=O)C4=CC=CC(C)=C4

Description

This fluorenylmethoxycarbonyl-protected amino acid derivative features a sterically hindered, electron-rich aromatic moiety that enhances solubility and stability during peptide synthesis. The m-tolyl group provides robust steric shielding, minimizing racemization while the fluoren-9-ylmethoxy carbonyl (Fmoc) handle enables efficient orthogonal deprotection under mild basic conditions.

Application

3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(m-tolyl)propanoic acid serves as a robust, bench-stable amino acid derivative for peptide synthesis, enabling efficient N-terminal protection with orthogonal deprotection under mild conditions. Its fluorenylmethoxycarbonyl (Fmoc) group provides excellent compatibility with standard coupling protocols, while the m-tolyl-substituted propanoic acid side chain enhances solubility and facilitates purification. Functions reliably in solid-phase and solution-phase workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 75.63
LogP 5.04952
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 6

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Functional Group Carboxylic Acid

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(m-tolyl)propanoic acid

CAS No. 284492-06-4

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