(R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole

Name: (R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole
Brand: ChemScene
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CAS No. 2757082-47-4
Cat. No. CS-0179441
Purity≥95%
MDL No.None

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(R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole|CS-0179441

Structure of 2757082-47-4

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General Information

CAS No. 2757082-47-4
Cat. No. CS-0179441
Purity ≥95%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₇H₁₉N₃O
Molecular Weight 281.35
Synonym(s) None
SMILES CC(C)(C)[C@@H]1COC(C2=NC(C3=CC=CC=N3)=CC=C2)=N1

Description

(R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole is a sterically hindered heterocyclic ligand featuring a bipyridine unit paired with a chiral dihydrooxazole scaffold. This configuration enables robust metal coordination in catalytic systems while maintaining stability under standard handling conditions. The tert-butyl group enhances solubility and resistance to decomposition.

Application

(R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole serves as a stable, bench-ready heterocyclic building block for transition metal catalysis and ligand development. Its fused bipyridine-oxazole scaffold enables coordination to palladium and ruthenium centers, facilitating cross-coupling reactions and catalytic cycles. The tert-butyl group enhances solubility and steric protection, while the dihydrooxazole ring maintains functional group tolerance under standard synthetic conditions. This compound functions effectively in modular synthesis of advanced ligands and catalyst precursors.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 47.37
LogP 3.3351
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 2

Key Words

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(R)-2-([2,2'-Bipyridin]-6-yl)-4-(tert-butyl)-4,5-dihydrooxazole

CAS No. 2757082-47-4

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