2-Bromo-5-(hydroxymethyl)phenol

Name: 2-Bromo-5-(hydroxymethyl)phenol
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CAS No. 2737-19-1
Cat. No. CS-W006136
Molecule weight203.03
Purity≥95%
MDL No.MFCD14705103

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2-Bromo-5-(hydroxymethyl)phenol|CS-W006136

Structure of 2737-19-1

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General Information

CAS No. 2737-19-1
Cat. No. CS-W006136
Purity ≥95%
MDL No. MFCD14705103
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇BrO₂
Molecular Weight 203.03
Synonym(s) 4-Bromo-3-hydroxybenzyl alcohol
SMILES OC1=CC(CO)=CC=C1Br

Description

This phenolic compound features a bromine substituent at the ortho position and a hydroxymethyl group at the para position relative to the phenolic OH, enabling selective functionalization in synthetic routes. The hydroxymethyl moiety offers a handle for derivatization, while the bromine serves as a reactive site for cross-coupling reactions. Bench-stable under standard conditions, it supports efficient access to complex aromatic architectures in medicinal chemistry and materials synthesis.

Application

2-Bromo-5-(hydroxymethyl)phenol serves as a versatile building block for functionalized aromatic scaffolds, enabling efficient derivatization via Suzuki-Miyaura and Stille couplings. The bromo group provides reliable electrophilic reactivity, while the hydroxymethyl functionality offers orthogonal handles for oxidation, protection, or further substitution—facilitating access to complex phenolic architectures with high synthetic flexibility and bench stability.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 40.46
LogP 1.647
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-5-(hydroxymethyl)phenol

CAS No. 2737-19-1

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