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CS-W001157 4
Total: USD 88.00

(Bis(trifluoroacetoxy)iodo)benzene

  • CAS No. 2712-78-9

  • Cat. No. CS-W011628
  • Purity≥98%
  • MDL No.MFCD00009672

*For research and further manufacturing use only, not for direct human use.

(Bis(trifluoroacetoxy)iodo)benzene|CS-W011628

Structure of 2712-78-9

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General Information

  • CAS No. 2712-78-9
  • Cat. No. CS-W011628
  • Purity ≥98%
  • MDL No. MFCD00009672
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₅F₆IO₄
  • Molecular Weight 430.04
  • Synonym(s) Phenyliodine(III) bis(trifluoroacetate)
  • SMILES O=C(OI(C1=CC=CC=C1)OC(C(F)(F)F)=O)C(F)(F)F

Description

Reactant or reagent for:Pummerer-like reactionsChemoselective deprotection of dimethoxybenzyl ethersMediating oxidative cycloisomerizationTosyloxylation of anilides

Synthesis

  • Route1
    • In-stock
      Iodobenzene|CS-W008603
      591-50-4
    • null|null
      76-05-1
    • ~96%
    • In-stock
      (Bis(trifluoroacetoxy)iodo)benzene|CS-W011628
      2712-78-9

    References

    • Zagulyaeva, Aleksandra A.; Yusubov, Mekhman S.; Zhdankin, Viktor V. Journal of Organic Chemistry, 2010 , vol. 75, # 6 p. 2119 - 2122
  • Route2
    • In-stock
      Iodobenzene|CS-W008603
      591-50-4
    • null|null
      407-25-0
    • ~86%
    • In-stock
      (Bis(trifluoroacetoxy)iodo)benzene|CS-W011628
      2712-78-9

    References

    • Kazmierczak, Pawel; Skulski, Lech Molecules, 2002 , vol. 7, # 11 p. 810 - 812
  • Route3
    • In-stock
      (Diacetoxyiodo)benzene|CS-W011998
      3240-34-4
    • null|null
      76-05-1
    • ~95%
    • In-stock
      (Bis(trifluoroacetoxy)iodo)benzene|CS-W011628
      2712-78-9

    References

    • Shabarov, Yu. S.; Pisanova, E. V.; Saginova, L. G. Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, p. 1685 - 1689 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 9 p. 1886 - 1892

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   2.8682
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   3

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