2-Bromo-4-fluoro-1,3-dimethylbenzene

Name: 2-Bromo-4-fluoro-1,3-dimethylbenzene
Brand: ChemScene
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CAS No. 26829-82-3
Cat. No. CS-0088931
Purity≥98%
MDL No.MFCD28016861

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Bromo-4-fluoro-1,3-dimethylbenzene|CS-0088931

Structure of 26829-82-3

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General Information

CAS No. 26829-82-3
Cat. No. CS-0088931
Purity ≥98%
MDL No. MFCD28016861
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrF
Molecular Weight 203.05
Synonym(s) 2-Bromo-4-fluoro-1,3-dimethyl-benzene
SMILES CC1=C(Br)C(C)=CC=C1F

Description

2-Bromo-4-fluoro-1,3-dimethylbenzene features a uniquely positioned bromo and fluoro substituent on a dimethylated benzene core, enabling selective functionalization in cross-coupling reactions. This electron-deficient aryl halide offers enhanced stability under standard conditions and facilitates efficient derivatization in pharmaceutical and agrochemical synthesis.

Application

2-Bromo-4-fluoro-1,3-dimethylbenzene serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling palladium-catalyzed cross-coupling reactions such as Suzuki-Miyaura and Stille couplings. The ortho-bromo and meta-fluoro substituents provide complementary reactivity for sequential functionalization, while the dimethyl groups enhance solubility and steric control. Bench-stable and readily purified by flash chromatography, it functions reliably in multi-step syntheses of complex aromatic scaffolds.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 0
LogP 3.20504
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-4-fluoro-1,3-dimethylbenzene

CAS No. 26829-82-3

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