2-Chloro-N,N-dimethylacetamide

Name: 2-Chloro-N,N-dimethylacetamide
Brand: ChemScene
Availability: InStock
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CAS No. 2675-89-0
Cat. No. CS-0008654
Purity≥98%
MDL No.MFCD00039360

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Chloro-N,N-dimethylacetamide|CS-0008654

Structure of 2675-89-0

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General Information

CAS No. 2675-89-0
Cat. No. CS-0008654
Purity ≥98%
MDL No. MFCD00039360
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄H₈ClNO
Molecular Weight 121.57
Synonym(s) N,N-Dimethylchloroacetamide; 2-Chloro-N,N-dimethylacetamide
SMILES O=C(N(C)C)CCl

Description

2-Chloro-N,N-dimethylacetamide (N,N-dimethylchloroacetamide) was used in the synthesis of (S)-carbinoxamine.

Application

2-Chloro-N,N-dimethylacetamide serves as a versatile acylating agent in synthetic organic chemistry, enabling efficient amide bond formation under mild conditions. Its chloroacetyl moiety facilitates nucleophilic substitution with amines and alcohols, offering high reactivity and compatibility with diverse functional groups. The compound exhibits excellent bench stability and ease of purification, making it well-suited for scalable synthesis and process development workflows.

Synthesis

Route1
- 506-59-2
- 79-04-9
- ~32%
- In-stock
  
  2675-89-0
References
- Miyazawa, Toshifumi; Tanaka, Kayoko; Ensatsu, Eiichi; Yanagihara, Ryoji; Yamada, Takashi Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 1 p. 87 - 93
Route2
- 124-40-3
- 79-04-9
- ~79%
- In-stock
  
  2675-89-0
References
- Kem, Kenneth M.; Nguyen, Nghi V.; Cross, Dennis J. Journal of Organic Chemistry, 1981 , vol. 46, p. 5188 - 5192
Route3
- 79-04-9
- 74-89-5
- ~%
- In-stock
  
  2675-89-0
References
- Haley, Gregory Jay; Kong, Norman; Liu, Emily Aijun; Simonsen, Klaus B.; Vu, Binh Thanh; Webber, Stephen Evan Patent: US2004/259884 A1, 2004 ; Location in patent: Page 15 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS05,GHS07
Signal Word : Danger	UN#: 3265
Class : 8	Packing Group : Ⅲ
Hazard Statements : H302-H314
Precautionary Statements : P260-P264-P270-P280-P301+P330+P331-P304+P340-P330-P363-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 20.31
LogP 0.3134
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Functional Group Chloride

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2-Chloro-N,N-dimethylacetamide

CAS No. 2675-89-0

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