(S)-2-Cl-Phox-Bn

Name: (S)-2-Cl-Phox-Bn
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CAS No. 2634687-64-0
Cat. No. CS-0145296
Purity≥95%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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General Information

CAS No. 2634687-64-0
Cat. No. CS-0145296
Purity ≥95%
MDL No. None
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₈H₂₃ClNOP
Molecular Weight 455.92
Synonym(s) (S)-4-Benzyl-2-(2-chloro-6-(diphenylphosphino)phenyl)-4,5-dihydrooxazole
SMILES ClC1=CC=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=C1C4=N[C@@H](CC5=CC=CC=C5)CO4

Description

(S)-2-Cl-Phox-Bn features a chiral benzyl-protected oxime scaffold with a chlorine atom at the ortho position, delivering enhanced stability and selective reactivity in asymmetric synthesis. This bench-stable derivative enables efficient coupling strategies in complex molecule assembly.

Application

(S)-2-Cl-Phox-Bn serves as a robust chiral auxiliary for asymmetric synthesis, enabling stereoselective C–C bond formation through well-established enolate chemistry. Its ortho-chlorophenoxymethyl group provides enhanced stability and facilitates straightforward purification, while the (S)-configuration ensures high diastereoselectivity in standard aldol and alkylation reactions. Functions reliably in bench-scale applications with excellent functional group tolerance and predictable reactivity.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 21.59
LogP 5.4863
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 6

Key Words

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(S)-2-Cl-Phox-Bn

CAS No. 2634687-64-0

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