Lot numbers can be found on the outside label of a product:
5-Bromoacenaphthenequinone
-
CAS No. 26254-35-3
- Cat. No. CS-0187764
- Purity≥95%
- MDL No.MFCD18448738
*For research and further manufacturing use only, not for direct human use.
Structure of 26254-35-3
Please choose your location and provide accurate information for you
| Size |
|
Price | Quantity | |||
|---|---|---|---|---|---|---|
|
* Please select Quantity before adding items. |
||||||
Recommended Products
General Information
- CAS No. 26254-35-3
- Cat. No. CS-0187764
- Purity ≥95%
- MDL No. MFCD18448738
- Storage Store at room temperature
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₂H₅BrO₂
- Molecular Weight 261.07
- Synonym(s) 1,2-Acenaphthylenedione, 5-bromo-
- SMILES O=C1C(C2=C3C1=CC=CC3=C(Br)C=C2)=O
Description
5-Bromoacenaphthenequinone features a bromine substituent at the 5-position of the acenaphthenequinone scaffold, enhancing its reactivity in cross-coupling processes. This electron-deficient quinone integrates readily into synthetic pathways requiring halogenated aromatic intermediates. The molecule exhibits bench-stable handling characteristics and maintains structural integrity under standard reaction conditions.
Application
5-Bromoacenaphthenequinone serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its well-defined bromine functionality. The acenaphthenequinone core provides a rigid, electron-deficient aromatic system that facilitates Diels-Alder cycloadditions and nucleophilic substitutions. Its bench-stable crystalline form simplifies handling and purification, making it suitable for iterative synthesis of complex polycyclic scaffolds and functionalized heterocycles in medicinal chemistry and materials science applications.
Synthesis
-
Route1
-
In-stock
82-86-0 - ~88%
-
In-stock
26254-35-3
References
-
Zhang, Hua; Fan, Jiangli; Wang, Jingyun; Dou, Bairui; Zhou, Fan; Cao, Jianfang; Qu, Junle; Cao, Zhi; Zhao, Weijie; Peng, Xiaojun Journal of the American Chemical Society, 2013 , vol. 135, # 46 p. 17469 - 17475
-
-
Route2
-
In-stock
2051-98-1 - ~49%
-
In-stock
26254-35-3
References
-
Patel, Vijay H.; Patel, Manish P.; Patel, Ranjan G. Heterocyclic Communications, 2001 , vol. 7, # 6 p. 599 - 606
-
-
Route3
-
34825-01-9 - ~91%
-
In-stock
26254-35-3
References
-
Tatsugi, Jiro; Okumura, Shigeo; Izawa, Yasuji Bulletin of the Chemical Society of Japan, 1986 , vol. 59, p. 3311 - 3313
-
Safety Information
Download SDS|
GHS Pictogram :
|
GHS No : GHS07
|
|
Signal Word : Warning
|
UN#: N/A
|
|
Class : N/A
|
Packing Group : N/A
|
|
Hazard Statements : H302-H315-H319-H335
|
|
|
Precautionary Statements : P261-P280-P302+P352
|
|
Quality Control
Computational Chemistry Data
- TPSA 34.14
- LogP 2.9813
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 0
Similar Products
Other Classifications
Recently Viewed Products
Leave US a Message
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Upload Pictures
|
|
Key Words
- 5-Bromoacenaphthenequinone sigma5-Bromoacenaphthenequinone manufacturer5-Bromoacenaphthenequinone price5-Bromoacenaphthenequinone structure5-Bromoacenaphthenequinone SDSbuy 5-Bromoacenaphthenequinone5-Bromoacenaphthenequinone supplier5-Bromoacenaphthenequinone uses5-Bromoacenaphthenequinone molecular weightprice of 5-Bromoacenaphthenequinone5-Bromoacenaphthenequinone chemical name formula of 5-Bromoacenaphthenequinone