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CS-W001157 4
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1,2:5,6-Bis-O-(1-methylethylidene)-α-D-allofuranose

  • CAS No. 2595-05-3

  • Cat. No. CS-W008335
  • Purity≥95%
  • MDL No.MFCD00135634

*For research and further manufacturing use only, not for direct human use.

1,2:5,6-Bis-O-(1-methylethylidene)-α-D-allofuranose|CS-W008335

Structure of 2595-05-3

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General Information

  • CAS No. 2595-05-3
  • Cat. No. CS-W008335
  • Purity ≥95%
  • MDL No. MFCD00135634
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₂₀O₆
  • Molecular Weight 260.29
  • Synonym(s) None
  • SMILES O[C@H]1[C@]2([H])[C@](OC(C)(O2)C)([H])O[C@]1([H])[C@@]3([H])COC(C)(O3)C

Description

This acetonide-protected D-allofuranose derivative features a rigid, sterically shielded glycosidic scaffold ideal for stereoselective glycosylation reactions. The 1,2:5,6-bis-O-(1-methylethylidene) protection pattern enhances stability and modulates reactivity in carbohydrate synthesis workflows.

Synthesis

  • Route1
    • null|null
      2847-00-9
    • ~94%
    • In-stock
      1,2:5,6-Bis-O-(1-methylethylidene)-α-D-allofuranose|CS-W008335
      2595-05-3

    References

    • Deshmukh, Abdul Rakeeb A. S.; Jayanthi, Arumugam; Thiagarajan, Kamanan; Puranik, Vedavati G.; Bhawal, Baburao M. Synthesis, 2004 , # 18 p. 2965 - 2974
  • Route2

    References

    • Ghosh, Subhash; Shashidhar; Dutta, Samit Kumar Tetrahedron Letters, 2006 , vol. 47, # 34 p. 6041 - 6044
  • Route3
    • null|null
      226943-46-0
    • ~89%
    • In-stock
      1,2:5,6-Bis-O-(1-methylethylidene)-α-D-allofuranose|CS-W008335
      2595-05-3

    References

    • Ramasamy, Kanda S.; Averett, Devron Synlett, 1999 , # 6 p. 709 - 712

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   66.38
  • LogP   0.3752
  • H_Acceptors   6
  • H_Donors   1
  • Rotatable_Bonds   1

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