2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl methacrylate

Name: 2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl methacrylate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 254900-07-7
Cat. No. CS-0167817
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl methacrylate|CS-0167817

Structure of 254900-07-7

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General Information

CAS No. 254900-07-7
Cat. No. CS-0167817
Purity ≥98%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₁₄O₄
Molecular Weight 222.24
Synonym(s) Methacrylic Acid 2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl Ester
SMILES C=C(C)C(OC1C2CC(C3C2)C1OC3=O)=O

Description

This methacrylate ester features a rigid, fused cyclopentane-furan core with a carbonyl group at the 2-position, enabling high reactivity in polymerization. The electron-deficient enone system enhances copolymerization efficiency, while the bulky methacrylate side chain provides steric control over chain growth.

Application

2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl methacrylate serves as a versatile bicyclic building block for synthesizing complex carbocyclic and heterocyclic scaffolds. Its α,β-unsaturated ester functionality enables efficient Michael additions and Diels–Alder cycloadditions, while the ketone group supports selective reductions and condensation reactions. The rigid, polycyclic core enhances stereochemical control in asymmetric synthesis, and the compound exhibits excellent bench stability and ease of purification, making it well-suited for iterative synthesis workflows in medicinal chemistry and natural product total synthesis.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

TPSA 52.6
LogP 1.0557
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Material Science Polymer Materials Macromolecular Monomer

Material Science Polymer/Macromolecule Reagents Photopolymer Reagents

Material Science Polymer/Macromolecule Reagents Monomers Acrylic Monomers

Key Words

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2-Oxohexahydro-2H-3,5-methanocyclopenta[b]furan-6-yl methacrylate

CAS No. 254900-07-7

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