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CS-W001157 4
Total: USD 88.00

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride

  • CAS No. 250285-32-6

  • Cat. No. CS-W001127
  • Purity≥97%
  • MDL No.MFCD02684545

*For research and further manufacturing use only, not for direct human use.

1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride|CS-W001127

Structure of 250285-32-6

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General Information

  • CAS No. 250285-32-6
  • Cat. No. CS-W001127
  • Purity ≥97%
  • MDL No. MFCD02684545
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₇H₃₇ClN₂
  • Molecular Weight 425.05
  • Synonym(s) None
  • SMILES CC(C)C1=C(N(C=C2)C=[N+]2C(C(C(C)C)=CC=C3)=C3C(C)C)C(C(C)C)=CC=C1.[Cl-]

Description

Used with palladium acetate to generate an N-heterocyclic carbene catalyst for carbonylative cross-coupling of pyridyl halides with aryl boronic acids.

Synthesis

  • Route1
    • null|null
      50-00-0
    • (1E)-N1,N2-bis(2,6-diisopropylphenyl)ethane-1,2-diimine|CS-0469030
      74663-75-5
    • ~88%
    • In-stock
      1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride|CS-W001127
      250285-32-6

    References

    • Tang, Pingping; Wang, Weike; Ritter, Tobias Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11482 - 11484
  • Route2
    • (1E)-N1,N2-bis(2,6-diisopropylphenyl)ethane-1,2-diimine|CS-0469030
      74663-75-5
    • null|null
      3188-13-4
    • ~94%
    • In-stock
      1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride|CS-W001127
      250285-32-6

    References

    • Higgins, Eleanor M.; Sherwood, Jennifer A.; Lindsay, Anita G.; Armstrong, James; Massey, Richard S.; Alder, Roger W.; O'Donoghue, Annmarie C. Chemical Communications, 2011 , vol. 47, # 5 p. 1559 - 1561
  • Route3
    • null|null
      1207373-09-8
    • ~99%
    • In-stock
      1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride|CS-W001127
      250285-32-6

    References

    • Fu, Ching-Feng; Lee, Chun-Chin; Liu, Yi-Hung; Peng, Shie-Ming; Warsink, Stefan; Elsevier, Cornelis J.; Chen, Jwu-Ting; Liu, Shiuh-Tzung Inorganic Chemistry, 2010 , vol. 49, # 6 p. 3011 - 3018

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS06,GHS09
Signal Word : Danger
UN#: 2811
Class : 6.1
Packing Group : Ⅱ
Hazard Statements : H300-H318-H335-H400-H410
Precautionary Statements : P261-P264-P270-P271-P273-P280-P391-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   8.81
  • LogP   4.2516
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   6

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