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CS-W001157 4
Total: USD 88.00

1-Bromo-4-(dimethoxymethyl)benzene

  • CAS No. 24856-58-4

  • Cat. No. CS-0150667
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

1-Bromo-4-(dimethoxymethyl)benzene|CS-0150667

Structure of 24856-58-4

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General Information

  • CAS No. 24856-58-4
  • Cat. No. CS-0150667
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₁BrO₂
  • Molecular Weight 231.09
  • Synonym(s) (4-Bromophenyl)dimethoxymethane
  • SMILES COC(C1=CC=C(C=C1)Br)OC

Description

1-Bromo-4-(dimethoxymethyl)benzene features a bromine substituent at the para position relative to a dimethoxymethyl group, enabling selective cross-coupling reactions. The dimethoxymethyl moiety enhances solubility and stability under standard conditions, while the aryl bromide serves as a reliable electrophilic handle in palladium-catalyzed transformations.

Synthesis

  • Route1
    • In-stock
      4-Bromobenzaldehyde|CS-W001138
      1122-91-4
    • null|null
      149-73-5
    • ~99%
    • In-stock
      1-Bromo-4-(dimethoxymethyl)benzene|CS-0150667
      24856-58-4

    References

    • Kim, Hyungwoo; Cha, Min Chul; Park, Hyun Woo; Chang, Ji Young Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 24 p. 5291 - 5297
  • Route2

    References

    • US5849911 A1, ; US 5849911 A
  • Route3
    • null|null
      67-56-1
    • In-stock
      4-Bromobenzaldehyde|CS-W001138
      1122-91-4
    • ~10%
    • In-stock
      1-Bromo-4-(dimethoxymethyl)benzene|CS-0150667
      24856-58-4

    References

    • Tateiwa, Jun-ichi; Horiuchi, Hiroki; Uemura, Sakae Journal of Organic Chemistry, 1995 , vol. 60, # 13 p. 4039 - 4043

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   2.7405
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   3

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