Lot numbers can be found on the outside label of a product:
N-Methoxybenzamide
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CAS No. 2446-51-7
- Cat. No. CS-0155863
- Purity≥98%
- MDL No.MFCD19439675
*For research and further manufacturing use only, not for direct human use.
Structure of 2446-51-7
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General Information
- CAS No. 2446-51-7
- Cat. No. CS-0155863
- Purity ≥98%
- MDL No. MFCD19439675
- Storage 4°C, sealed storage, away from moisture
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₈H₉NO₂
- Molecular Weight 151.16
- Synonym(s) N-methoxybenzenecarboximidic acid
- SMILES C1=CC=CC(=C1)C(NOC)=O
Description
N-Methoxybenzamide features a methoxy group attached to the nitrogen of a benzamide scaffold, delivering enhanced solubility and stability compared to its unsubstituted counterpart. This substitution pattern facilitates selective reactivity in amide bond formation and enables efficient incorporation into peptide-like architectures under mild conditions.
Application
N-Methoxybenzamide serves as a stable, bench-ready amide surrogate that facilitates nucleophilic acyl substitution under mild conditions. Its methoxy group enhances electrophilicity at the carbonyl carbon, enabling efficient coupling with amines, alcohols, and hydrides. Functions as a key building block in heterocycle synthesis and peptide-like scaffold construction, offering predictable reactivity and straightforward purification.
Synthesis
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Route1
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In-stock
593-56-6 -
98-88-4 - ~99%
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In-stock
2446-51-7
References
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Miyata, Okiko; Koizumi, Tomoko; Asai, Hiroshi; Iba, Ryuichi; Naito, Takeaki Tetrahedron, 2004 , vol. 60, # 17 p. 3893 - 3914
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References
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Bailen, Miguel A.; Chinchilla, Rafael; Dodsworth, David J.; Najera, Carmen Tetrahedron Letters, 2001 , vol. 42, # 30 p. 5013 - 5016
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Route3
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32685-16-8 -
74-88-4
- ~46%
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In-stock
2446-51-7
References
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Digianantonio, Katherine M.; Glover, Stephen A.; Johns, Jennifer P.; Rosser, Adam A. Organic and Biomolecular Chemistry, 2011 , vol. 9, # 11 p. 4116 - 4126
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 38.33
- LogP 0.9778
- H_Acceptors 2
- H_Donors 1
- Rotatable_Bonds 2
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