(2,2'-Bipyridine)nickel dichloride

Name: (2,2'-Bipyridine)nickel dichloride
Brand: ChemScene
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CAS No. 22775-90-2
Cat. No. CS-0163439
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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(2,2'-Bipyridine)nickel dichloride|CS-0163439

Structure of 22775-90-2

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General Information

CAS No. 22775-90-2
Cat. No. CS-0163439
Purity ≥98%
MDL No. None
Storage 4°C, sealed storage, away from moisture
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₈Cl₂N₂Ni
Molecular Weight 285.78
Synonym(s) None
SMILES Cl[Ni]1(Cl)[N]2=C(C=CC=C2)C3=CC=CC=[N]31

Application

(2,2'-Bipyridine)nickel dichloride serves as a robust, bench-stable precatalyst for cross-coupling reactions, enabling efficient C–C and C–heteroatom bond formation under mild conditions. Its well-defined coordination geometry facilitates reliable catalytic activity in Negishi, Suzuki-Miyaura, and Sonogashira transformations. The bipyridyl ligand imparts enhanced solubility and stability, while the Ni(II) center offers predictable reactivity with organometallic partners. Functions effectively in both homogeneous and heterogeneous systems, supporting scalable synthesis workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Catalysis Non-Precious Metal Catalysis

Catalysis C-H Activation Nickel Compounds

Catalysis Cross-coupling Reaction using Transition Metal Catalysts Nickel Catalysts

Catalysis Transition Elements Nickel

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Key Words

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(2,2'-Bipyridine)nickel dichloride

CAS No. 22775-90-2

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