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CS-W001157 4
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2-Bromo-9,9-dihexyl-9H-fluorene

  • CAS No. 226070-05-9

  • Cat. No. CS-0186592
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

2-Bromo-9,9-dihexyl-9H-fluorene|CS-0186592

Structure of 226070-05-9

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General Information

  • CAS No. 226070-05-9
  • Cat. No. CS-0186592
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₅H₃₃Br
  • Molecular Weight 413.43
  • Synonym(s) 9H-Fluorene, 2-bromo-9,9-dihexyl-
  • SMILES CCCCCCC1(CCCCCC)C2=CC=CC=C2C3=C1C=C(C=C3)Br

Description

2-Bromo-9,9-dihexyl-9H-fluorene features a sterically shielded fluorene core with a bromine substituent at the 2-position and two long alkyl chains at the 9-position. This configuration enhances solubility and stability while enabling efficient coupling in cross-coupling reactions. The molecule serves as a robust building block for conjugated polymers and optoelectronic materials.

Application

2-Bromo-9,9-dihexyl-9H-fluorene serves as a versatile fluorene-based building block for the synthesis of conjugated polymers and optoelectronic materials. The bromine substituent enables efficient Pd-catalyzed cross-coupling reactions, while the bulky dihexyl groups enhance solubility and processability. Its stability under standard reaction conditions facilitates reliable incorporation into extended π-conjugated architectures.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   8.6564
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   10

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