2-Bromo-1,10-phenanthroline

Name: 2-Bromo-1,10-phenanthroline
Brand: ChemScene
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CAS No. 22426-14-8
Cat. No. CS-W004619
Purity≥95%
MDL No.MFCD13152102

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 22426-14-8

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General Information

CAS No. 22426-14-8
Cat. No. CS-W004619
Purity ≥95%
MDL No. MFCD13152102
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₇BrN₂
Molecular Weight 259.10
Synonym(s) 2-Bromo-1,10-phenant
SMILES BrC1=NC2=C3C(C=CC=N3)=CC=C2C=C1

Application

2-Bromo-1,10-phenanthroline serves as a versatile ligand precursor in transition metal catalysis, enabling palladium- and copper-mediated coupling reactions. Its bromine substituent facilitates cross-coupling transformations while maintaining the rigid aromatic framework essential for chelation. The compound exhibits excellent bench stability, ease of purification, and compatibility with diverse functional groups, making it well-suited for constructing metallacyclic intermediates and complex heterocyclic scaffolds in synthetic and medicinal chemistry workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS05,GHS06,GHS09
Signal Word : Danger	UN#: 2811
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301-H315-H318-H410
Precautionary Statements : P264-P270-P273-P280-P302+P352-P330-P362+P364-P391-P405-P501

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Computational Chemistry Data

TPSA 25.78
LogP 3.5455
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Phenanthroline Ligands

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Phenanthroline Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Phenanthroline Ligands

Key Words

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2-Bromo-1,10-phenanthroline

CAS No. 22426-14-8

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