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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

  • CAS No. 21797-13-7

  • Cat. No. CS-0080599
  • Purity≥97%
  • MDL No.MFCD00043297

*For research and further manufacturing use only, not for direct human use.

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate|CS-0080599

Structure of 21797-13-7

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General Information

  • CAS No. 21797-13-7
  • Cat. No. CS-0080599
  • Purity ≥97%
  • MDL No. MFCD00043297
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula Pd(CH₃CN)₄(BF₄)₂
  • Molecular Weight 444.24
  • Synonym(s) NSC 307191; Palladium(II) tetrafluoroborate tetraacetonitrile complex
  • SMILES [Pd(CH3CN)4(BF4)2]

Description

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligandsPrecursor for:Synthesis of dendritic SCS-pincer palladium complexesPalladium complexes of click ligandsDipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination

Synthesis

  • Route1

    References

    • Journal of the American Chemical Society, , vol. 129, # 8 p. 2246 - 2247

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H332
Precautionary Statements : P261-P271-P304+P340

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Computational Chemistry Data

  • TPSA   0
  • LogP   0.6361
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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