(2-Amino-5-bromophenyl)methanol

Name: (2-Amino-5-bromophenyl)methanol
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CAS No. 20712-12-3
Cat. No. CS-W005467
Purity≥97%
MDL No.MFCD08234509

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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(2-Amino-5-bromophenyl)methanol|CS-W005467

Structure of 20712-12-3

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General Information

CAS No. 20712-12-3
Cat. No. CS-W005467
Purity ≥97%
MDL No. MFCD08234509
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈BrNO
Molecular Weight 202.05
Synonym(s) Benzenemethanol, 2-amino-5-bromo-
SMILES OCC1=CC(Br)=CC=C1N

Description

This bench-stable arylmethanol features a brominated aromatic ring and a primary alcohol group, enabling direct incorporation into cross-coupling reactions. The para-positioned amino substituent enhances reactivity in Suzuki-Miyaura processes, while the hydroxyl moiety offers a handle for derivatization.

Application

(2-Amino-5-bromophenyl)methanol serves as a versatile building block for the synthesis of brominated aniline derivatives and heterocyclic scaffolds. Its amino and hydroxymethyl groups enable sequential functionalization, with the amine facilitating electrophilic substitution and the alcohol supporting orthogonal protection or coupling reactions. The compound exhibits good bench stability and is compatible with standard purification techniques, making it well-suited for medicinal chemistry campaigns and process development workflows.

Synthesis

Route1
- In-stock
  
  52727-57-8
- ~95%
- In-stock
  
  20712-12-3
References
- He, Yong; Mahmud, Hossen; Wayland, Brian R; Dias, H.V.Rasika; Lovely, Carl J Tetrahedron Letters, 2002 , vol. 43, # 7 p. 1171 - 1174
Route2
- In-stock
  
  5794-88-7
- ~97%
- In-stock
  
  20712-12-3
References
- Jia, Min-Qiang; You, Shu-Li ACS Catalysis, 2013 , vol. 3, # 4 p. 622 - 624
Route3
- 13292-87-0
- In-stock
  
  5794-88-7
- ~99%
- In-stock
  
  20712-12-3
References
- Takeda Chemical Industries, Ltd. Patent: US6166006 A1, 2000 ; US 6166006 A

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 46.25
LogP 1.5236
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Alcohol

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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(2-Amino-5-bromophenyl)methanol

CAS No. 20712-12-3

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