[1,1'-Biphenyl]-3,3'-diamine

Name: [1,1'-Biphenyl]-3,3'-diamine
Brand: ChemScene
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CAS No. 2050-89-7
Cat. No. CS-0088809
Purity≥97%
MDL No.MFCD00210852

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 2050-89-7
Cat. No. CS-0088809
Purity ≥97%
MDL No. MFCD00210852
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₁₂N₂
Molecular Weight 184.24
Synonym(s) 1,1'-biphenyl-3,3'-diamine
SMILES NC1=CC(C2=CC=CC(N)=C2)=CC=C1

Description

1,1'-Biphenyl]-3,3'-diamine features two amino groups positioned meta to the biphenyl linkage, enabling effective coordination in transition metal complexes. This electron-rich scaffold integrates readily into ligand architectures for catalysis and materials science applications. The molecule exhibits enhanced stability under standard conditions and facilitates modular derivatization through selective functionalization at the amine sites.

Synthesis

Route1
- 958-96-3
- ~98%
- In-stock
  
  2050-89-7
References
- Northwestern University; Silverman, Richard B.; Huang, He; Jing, Qing Patent: US2014/66635 A1, 2014 ; Location in patent: Paragraph 0027 ;
Route2
- In-stock
  
  30418-59-8
- 591-19-5
- ~74%
- In-stock
  
  2050-89-7
References
- Reuter, Raphael; Wegner, Hermann A. Chemistry - A European Journal, 2011 , vol. 17, # 10 p. 2987 - 2995
Route3
- 613-35-4
- ~%
- In-stock
  
  2050-89-7
References
- Journal of the American Chemical Society, , vol. 115, # 11 p. 4532 - 4539

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS06,GHS08,GHS09
Signal Word : Danger	UN#: 1885
Class : 6.1	Packing Group : Ⅱ
Hazard Statements : H302-H350-H410
Precautionary Statements : P264-P270-P273-P280-P330-P391-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 52.04
LogP 2.518
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Catalysts and Ligands Ligands Diamine Ligands BINAM Ligands

Catalysis Nitrogen-Donor Ligands Amine Ligands

Material Science Material Building Blocks Covalent Organic Frameworks (COFs) Linkers Amine Linkers

Material Science Polymer/Macromolecule Reagents Covalent Organic Frameworks (COFs) Linkers Amine Linkers

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[1,1'-Biphenyl]-3,3'-diamine

CAS No. 2050-89-7

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