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CS-W001157 4
Total: USD 88.00

4-(Diphenylamino)benzeneboronic acid

  • CAS No. 201802-67-7

  • Cat. No. CS-W000896
  • Purity≥96%
  • MDL No.MFCD06798117

*For research and further manufacturing use only, not for direct human use.

4-(Diphenylamino)benzeneboronic acid|CS-W000896

Structure of 201802-67-7

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General Information

  • CAS No. 201802-67-7
  • Cat. No. CS-W000896
  • Purity ≥96%
  • MDL No. MFCD06798117
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₈H₁₆BNO₂
  • Molecular Weight None
  • Synonym(s) None
  • SMILES OB(O)C1=CC=C(N(C2=CC=CC=C2)C3=CC=CC=C3)C=C1

Application

4-(Diphenylamino)benzeneboronic acid serves as a versatile Suzuki-Miyaura coupling partner, enabling efficient construction of biaryl scaffolds with excellent functional group tolerance. The diphenylamino group enhances electronic modulation and improves solubility, while the boronic acid moiety offers robust stability under ambient conditions and facilitates straightforward purification. This compound functions reliably in cross-coupling reactions for advanced materials and pharmaceutical intermediates.

Synthesis

  • Route1

    References

    • Wu, Wenting; Cheng, Chuanhui; Wu, Wanhua; Guo, Huimin; Ji, Shaomin; Song, Peng; Han, Keli; Zhao, Jianzhang; Zhang, Xin; Wu, Yubo; Du, Guotong European Journal of Inorganic Chemistry, 2010 , # 29 p. 4683 - 4696
  • Route2
    • null|null
      121-43-7
    • In-stock
      4-Bromo-N,N-diphenylaniline|CS-W002829
      36809-26-4
    • ~85%
    • In-stock
      4-(Diphenylamino)benzeneboronic acid|CS-W000896
      201802-67-7

    References

    • Wu, Wenting; Cheng, Chuanhui; Wu, Wanhua; Guo, Huimin; Ji, Shaomin; Song, Peng; Han, Keli; Zhao, Jianzhang; Zhang, Xin; Wu, Yubo; Du, Guotong European Journal of Inorganic Chemistry, 2010 , # 29 p. 4683 - 4696
  • Route3
    • null|null
      5419-55-6
    • In-stock
      4-Bromo-N,N-diphenylaniline|CS-W002829
      36809-26-4
    • ~90%
    • In-stock
      4-(Diphenylamino)benzeneboronic acid|CS-W000896
      201802-67-7

    References

    • Idemitsu Kosan Co., Ltd.; ITO Mitsunori; OGIWARA Toshinari; NISHIMURA Kazuki; INOUE Tetsuya; HIBINO Kumiko Patent: EP2602243 A1, 2013 ; Location in patent: Paragraph 0202; 0221 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   43.7
  • LogP   2.8362
  • H_Acceptors   3
  • H_Donors   2
  • Rotatable_Bonds   4

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