2-Amino-5-bromo-3-fluorophenol

Name: 2-Amino-5-bromo-3-fluorophenol
Brand: ChemScene
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CAS No. 186309-73-9
Cat. No. CS-0521137
Purity≥98%
MDL No.MFCD28348526

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Amino-5-bromo-3-fluorophenol|CS-0521137

Structure of 186309-73-9

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General Information

CAS No. 186309-73-9
Cat. No. CS-0521137
Purity ≥98%
MDL No. MFCD28348526
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₅BrFNO
Molecular Weight 206.01
Synonym(s) 4-Bromo-2-fluoro-6-hydroxyaniline
SMILES OC1=CC(Br)=CC(F)=C1N

Description

2-Amino-5-bromo-3-fluorophenol features a strategically positioned amino group flanked by bromo and fluoro substituents, enabling precise functionalization in pharmaceutical intermediates. This electron-deficient phenolic scaffold offers enhanced reactivity in cross-coupling and cyclization reactions, with bench-stable handling under standard conditions.

Application

2-Amino-5-bromo-3-fluorophenol serves as a versatile building block in medicinal chemistry, enabling efficient access to substituted heterocycles and pharmaceutical intermediates. Its orthogonal functional groups—amino, bromo, and fluoro—facilitate sequential coupling reactions under standard cross-coupling conditions. The compound exhibits good bench stability and is readily purified by recrystallization, supporting reliable use in multi-step syntheses.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H317-H319
Precautionary Statements : P261-P264-P272-P280-P302+P352-P362+P364-P501

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Computational Chemistry Data

TPSA 46.25
LogP 1.876
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Phenol

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Amino-5-bromo-3-fluorophenol

CAS No. 186309-73-9

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