Lot numbers can be found on the outside label of a product:
(R)-MeO-Cl-BIPHEP
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CAS No. 185913-97-7
- Cat. No. CS-0086659
- Purity≥97%
- MDL No.None
*For research and further manufacturing use only, not for direct human use.
Structure of 185913-97-7
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General Information
- CAS No. 185913-97-7
- Cat. No. CS-0086659
- Purity ≥97%
- MDL No. None
- Storage 4°C, protect from light, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₃₈H₃₀Cl₂O₂P₂
- Molecular Weight 651.50
- Synonym(s) None
- SMILES COC1=C(Cl)C=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=C1C4=C(OC)C(Cl)=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6
Description
(R)-MeO-Cl-BIPHEP is a chiral diphosphine ligand featuring a methoxy-substituted biphenyl backbone and a chlorine atom at the 3-position, enabling high enantioselectivity in palladium-catalyzed cross-coupling reactions. This bench-stable, moisture-tolerant ligand integrates seamlessly into asymmetric catalysis workflows, delivering consistent stereocontrol with broad functional group compatibility.
Synthesis
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Route1
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185836-54-8 - ~90%
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In-stock
185913-97-7
References
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Pohl, Torsten; Prinz, Thomas; Giffels, Guido; Sirges, Wolfram Patent: US2002/58814 A1, 2002 ;
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 18.46
- LogP 8.194
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 9
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Key Words
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