4-Bromo-N,N-dimethylbenzamide

Name: 4-Bromo-N,N-dimethylbenzamide
Brand: ChemScene
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CAS No. 18469-37-9
Cat. No. CS-0130734
Purity≥98%
MDL No.MFCD00463696

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4-Bromo-N,N-dimethylbenzamide|CS-0130734

Structure of 18469-37-9

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General Information

CAS No. 18469-37-9
Cat. No. CS-0130734
Purity ≥98%
MDL No. MFCD00463696
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₀BrNO
Molecular Weight 228.09
Synonym(s) N,N-Dimethyl p-bromobenzamide
SMILES O=C(N(C)C)C1=CC=C(Br)C=C1

Description

4-Bromo-N,N-dimethylbenzamide is a bench-stable, moisture-tolerant aryl bromide featuring a sterically hindered dimethylamino group. This compound integrates seamlessly into cross-coupling reactions, serving as a reliable building block for functionalized aromatic scaffolds in medicinal chemistry and materials science applications.

Application

4-Bromo-N,N-dimethylbenzamide serves as a versatile building block in medicinal chemistry and cross-coupling synthesis. The bromo group enables palladium-catalyzed transformations such as Suzuki, Stille, and Negishi couplings, while the N,N-dimethylamide functions as a stable, electron-withdrawing directing group. Its bench-stable nature and compatibility with diverse reaction conditions facilitate efficient construction of complex aryl scaffolds and API intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319
Precautionary Statements : P264-P270-P280-P301+P310-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362+P364-P501

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Computational Chemistry Data

TPSA 20.31
LogP 2.1509
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-Bromo-N,N-dimethylbenzamide

CAS No. 18469-37-9

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