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CS-W001157 4
Total: USD 88.00

tert-Butyldimethylsilanol

  • CAS No. 18173-64-3

  • Cat. No. CS-0154947
  • Purity≥98%
  • MDL No.MFCD00010673

*For research and further manufacturing use only, not for direct human use.

tert-Butyldimethylsilanol|CS-0154947

Structure of 18173-64-3

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General Information

  • CAS No. 18173-64-3
  • Cat. No. CS-0154947
  • Purity ≥98%
  • MDL No. MFCD00010673
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₁₆OSi
  • Molecular Weight 132.28
  • Synonym(s) tert-Butyl-hydroxy-Dimethylsilane
  • SMILES CC(C)(C)[Si](C)(C)O

Description

tert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:For the preparation of -chiral ether derivatives by catalytic asymmetric allylic substitution.As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.In the synthesis of enol silyl ethers.

Synthesis

  • Route1
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      74812-76-3
    • ~%
    • In-stock
      tert-Butyldimethylsilanol|CS-0154947
      18173-64-3
    • null|null
      67-64-1

    References

    • Journal of the American Chemical Society, , vol. 102, # 18 p. 5835 - 5838
  • Route2
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      74812-77-4
    • ~%
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      765-43-5
    • In-stock
      tert-Butyldimethylsilanol|CS-0154947
      18173-64-3

    References

    • Journal of the American Chemical Society, , vol. 102, # 18 p. 5835 - 5838
  • Route3
    • null|null
      354799-92-1
    • ~%
    • In-stock
      tert-Butyldimethylsilanol|CS-0154947
      18173-64-3
    • In-stock
      2-((tert-Butyldimethylsilyl)oxy)ethanol|CS-W019612
      102229-10-7

    References

    • Journal of the Chemical Society. Perkin Transactions 1, , # 9 p. 955 - 977

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Warning
UN#: 1987
Class : 3
Packing Group : Ⅲ
Hazard Statements : H225-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P260-P261-P264-P271-P280-P302+P352-P304+P340-P340-P362-P370+P378-P403-P405-P501

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Computational Chemistry Data

  • TPSA   20.23
  • LogP   1.9839
  • H_Acceptors   1
  • H_Donors   1
  • Rotatable_Bonds   0

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