Methyl 6-chloro-5-nitropicolinate

Name: Methyl 6-chloro-5-nitropicolinate
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CAS No. 1803583-09-6
Cat. No. CS-0127772
Purity≥95%
MDL No.MFCD28139347

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 6-chloro-5-nitropicolinate|CS-0127772

Structure of 1803583-09-6

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General Information

CAS No. 1803583-09-6
Cat. No. CS-0127772
Purity ≥95%
MDL No. MFCD28139347
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅ClN₂O₄
Molecular Weight 216.58
Synonym(s) methyl 6-chloro-5-nitropyridine-2-carboxylate
SMILES O=C(OC)C1=NC(Cl)=C([N+]([O-])=O)C=C1

Description

Methyl 6-chloro-5-nitropicolinate is a bench-stable, electron-deficient heterocyclic ester featuring a chlorinated pyridine core. This compound integrates readily into cross-coupling and nucleophilic substitution workflows, offering high reactivity at the C6 position. The para-nitro group enhances electrophilicity, while the methyl ester enables straightforward derivatization.

Application

Methyl 6-chloro-5-nitropicolinate serves as a versatile building block in heterocyclic synthesis, enabling efficient access to substituted pyridine scaffolds. Its ortho-activated chloro and nitro groups facilitate sequential functionalization via nucleophilic substitution and reduction protocols. The ester moiety supports further derivatization, while the compound exhibits good bench stability and ease of purification—ideal for medicinal chemistry campaigns and process-scale applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 82.33
LogP 1.4298
H_Acceptors 5
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

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Methyl 6-chloro-5-nitropicolinate

CAS No. 1803583-09-6

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