Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)

Name: Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)
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CAS No. 179162-34-6
Cat. No. CS-0081920
Purity≥95%
MDL No.MFCD04974246

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Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)|CS-0081920

Structure of 179162-34-6

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Description

Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) is a chiral dirhodium catalyst featuring four proline-derived ligands with hydrophobic dodecylphenylsulfonyl groups. This design enhances solubility in organic media while maintaining high enantioselectivity in C–H functionalization and cycloaddition reactions. The catalyst operates under mild conditions, enabling efficient asymmetric synthesis of complex scaffolds.

General Information

CAS No. 179162-34-6
Cat. No. CS-0081920
Purity ≥95%
MDL No. MFCD04974246
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉₂H₁₄₄N₄O₁₆Rh₂S₄
Molecular Weight 1896.22
Synonym(s) Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)
SMILES O=C(O)[C@H]1CCCN1S(C2=CC=C(CCCCCCCCCCCC)C=C2)(=O)=O.[Rh][Rh]

Computational Chemistry Data

TPSA 74.68
LogP 5.3827
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 14

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P262-P280-P304+P340-P501

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Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)

CAS No. 179162-34-6

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