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CS-W001157 4
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Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)

  • CAS No. 179162-34-6

  • Cat. No. CS-0081920
  • Purity≥95%
  • MDL No.MFCD04974246

*For research and further manufacturing use only, not for direct human use.

Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)|CS-0081920

Structure of 179162-34-6

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General Information

  • CAS No. 179162-34-6
  • Cat. No. CS-0081920
  • Purity ≥95%
  • MDL No. MFCD04974246
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉₂H₁₄₄N₄O₁₆Rh₂S₄
  • Molecular Weight 1896.22
  • Synonym(s) Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)
  • SMILES O=C(O)[C@H]1CCCN1S(C2=CC=C(CCCCCCCCCCCC)C=C2)(=O)=O.[Rh][Rh]

Description

Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) is a chiral dirhodium catalyst featuring four proline-derived ligands with hydrophobic dodecylphenylsulfonyl groups. This design enhances solubility in organic media while maintaining high enantioselectivity in C–H functionalization and cycloaddition reactions. The catalyst operates under mild conditions, enabling efficient asymmetric synthesis of complex scaffolds.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P262-P280-P304+P340-P501

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Computational Chemistry Data

  • TPSA   74.68
  • LogP   5.3827
  • H_Acceptors   3
  • H_Donors   1
  • Rotatable_Bonds   14

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