Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate

Name: Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate
Brand: ChemScene
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CAS No. 1762-45-4
Cat. No. CS-0089088
Purity≥95%
MDL No.MFCD30531632

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate|CS-0089088

Structure of 1762-45-4

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General Information

CAS No. 1762-45-4
Cat. No. CS-0089088
Purity ≥95%
MDL No. MFCD30531632
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₁₂N₂O₄
Molecular Weight 272.26
Synonym(s) 5,5'-Dimethoxycarbonyl-2,2'-bipyridine
SMILES O=C(OC)C1=CN=C(C=C1)C=2N=CC(=CC2)C(=O)OC

Description

Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate features a rigid bipyridine core with ester-functionalized positions enabling coordination to transition metals. The dual carboxylate groups enhance solubility in polar solvents and facilitate integration into metal-organic frameworks. This ligand offers predictable geometry for chelation and stability under standard bench conditions.

Application

Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate serves as a versatile bifunctional building block in transition metal catalysis and coordination chemistry. Its rigid bipyridyl core provides strong chelation for metals such as ruthenium and iron, while the ester groups enable further derivatization via hydrolysis or nucleophilic substitution. The compound exhibits excellent bench stability and facilitates modular synthesis of luminescent complexes and redox-active materials.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 78.38
LogP 1.7168
H_Acceptors 6
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Bipyridine Ligands

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

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Dimethyl [2,2'-bipyridine]-5,5'-dicarboxylate

CAS No. 1762-45-4

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