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CS-W001157 4
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1-Butyl-3-methylimidazolium hexafluorophosphate

  • CAS No. 174501-64-5

  • Cat. No. CS-W007844
  • Purity≥98%
  • MDL No.MFCD03093295

*For research and further manufacturing use only, not for direct human use.

1-Butyl-3-methylimidazolium hexafluorophosphate|CS-W007844

Structure of 174501-64-5

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General Information

  • CAS No. 174501-64-5
  • Cat. No. CS-W007844
  • Purity ≥98%
  • MDL No. MFCD03093295
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₅F₆N₂P
  • Molecular Weight 284.18
  • Synonym(s) 1-n-Butyl-3-methylimidazolium hexafluorophosphate
  • SMILES C[N+]1=CN(CCCC)C=C1.F[P-](F)(F)(F)(F)F

Description

BMIMPF6 is used as an efficient reaction medium for various synthetic and catalytic transformations.1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions. It can also be used as a medium for reactions such as: Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.Lipase-catalyzed enantioselective acylation of allylic alcohols.Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.

Synthesis

  • Route1

    References

    • Liu, Ling-Yan; Wang, Bing; Yang, Hong-Mei; Chang, Wei-Xing; Li, Jing Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5636 - 5639
  • Route2
    • In-stock
      1-Methylimidazole|CS-W008580
      616-47-7
    • null|null
      109-69-3
    • ~92%
    • In-stock
      1-Butyl-3-methylimidazolium hexafluorophosphate|CS-W007844
      174501-64-5

    References

    • Solvent Innovation GmbH Patent: EP1182197 A1, 2002 ; Location in patent: Page 9-10 ;
  • Route3

    References

    • Alcalde, Ermitas; Dinares, Immaculada; Ibanez, Anna; Mesquida, Neus Molecules, 2012 , vol. 17, # 4 p. 4007 - 4027

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

  • TPSA   8.81
  • LogP   4.4951
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   3

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