6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one

Name: 6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one
Brand: ChemScene
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CAS No. 165730-10-9
Cat. No. CS-0438297
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one|CS-0438297

Structure of 165730-10-9

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General Information

CAS No. 165730-10-9
Cat. No. CS-0438297
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₁₁BrO
Molecular Weight 239.11
Synonym(s) 6-BROMO-2,3-DIHYDRO-2,2-DIMETHYL-1H-INDEN-1-ONE
SMILES O=C1C(C)(C)CC2=C1C=C(Br)C=C2

Description

6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one is a sterically hindered bromo-ketone featuring a rigid indenone core. This bench-stable electrophile integrates readily into transition-metal-catalyzed cross-coupling reactions, offering efficient access to functionalized aromatic systems under mild conditions.

Application

6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted indene scaffolds via palladium-catalyzed cross-coupling reactions. The bromine atom facilitates C–C bond formation under standard Suzuki, Stille, or Negishi conditions, while the sterically hindered dimethyl-substituted ring enhances bench stability and simplifies purification. This compound functions as a key intermediate in the construction of complex heterocycles and bioactive molecules.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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Computational Chemistry Data

TPSA 17.07
LogP 3.2141
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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6-Bromo-2,2-dimethyl-2,3-dihydro-1H-inden-1-one

CAS No. 165730-10-9

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