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CS-W001157 4
Total: USD 88.00

5,5'-Dibromo-2,2'-bipyridine

  • CAS No. 15862-18-7

  • Cat. No. CS-W004618
  • Purity≥95%
  • MDL No.MFCD06657883

*For research and further manufacturing use only, not for direct human use.

5,5'-Dibromo-2,2'-bipyridine|CS-W004618

Structure of 15862-18-7

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General Information

  • CAS No. 15862-18-7
  • Cat. No. CS-W004618
  • Purity ≥95%
  • MDL No. MFCD06657883
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₆Br₂N₂
  • Molecular Weight 313.98
  • Synonym(s) 5,5'-Dibromo-2,2'-bipyridyl
  • SMILES BrC1=CC=C(N=C1)C2=NC=C(Br)C=C2

Description

5,5'-Dibromo-2,2'-bipyridine features two bromine atoms at the 5 and 5' positions of the bipyridine scaffold, imparting enhanced electron-withdrawing character and improved metal coordination stability. This structural modification enhances its utility in transition metal catalysis and as a ligand in photoactive complexes. The dibromo substitution pattern improves solubility in organic solvents and facilitates purification under standard bench conditions.

Synthesis

  • Route1

    References

    • Bruce, James I.; Chambron, Jean-Claude; Koelle, Philipp; Sauvage, Jean-Pierre Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 10 p. 1226 - 1231
  • Route2
    • In-stock
      3-Bromopyridine|CS-0008362
      626-55-1
    • null|null
      16663-58-4
    • ~60%
    • In-stock
      5,5'-Dibromo-2,2'-bipyridine|CS-W004618
      15862-18-7

    References

    • Dhau, Jaspreet S.; Singh, Amritpal; Kasetti, Yoganjaneyulu; Bhatia, Sonam; Bharatam, Parsad V.; Brandao, Paula; Felix, Vitor; Singh, Kamal N. Tetrahedron, 2013 , vol. 69, # 48 p. 10284 - 10291
  • Route3

    References

    • US2006/30714 A1, ; Page/Page column 6 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   25.78
  • LogP   3.6686
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   1

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