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CS-W001157 4
Total: USD 88.00

Diethyl 1,1-cyclopropanedicarboxylate

  • CAS No. 1559-02-0

  • Cat. No. CS-W022623
  • Purity≥98%
  • MDL No.MFCD00001283

*For research and further manufacturing use only, not for direct human use.

Diethyl 1,1-cyclopropanedicarboxylate|CS-W022623

Structure of 1559-02-0

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General Information

  • CAS No. 1559-02-0
  • Cat. No. CS-W022623
  • Purity ≥98%
  • MDL No. MFCD00001283
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₄O₄
  • Molecular Weight 186.21
  • Synonym(s) Diethyl-1,1-cyclopropane dicarboxylate
  • SMILES C(C)OC(C1(C(OCC)=O)CC1)=O

Description

Diethyl 1,1-cyclopropanedicarboxylate features a strained cyclopropane ring flanked by two ester groups, enabling unique reactivity in cycloaddition and functionalization processes. This bench-stable, moisture-tolerant reagent integrates readily into synthetic sequences requiring rigid, electron-deficient frameworks.

Synthesis

  • Route1
    • null|null
      106-93-4
    • null|null
      105-53-3
    • ~95%
    • In-stock
      Diethyl 1,1-cyclopropanedicarboxylate|CS-W022623
      1559-02-0

    References

    • Chang, Xiao-Wei; Han, Qing-Chuan; Jiao, Zhi-Gang; Weng, Lin-Hong; Zhang, Dan-Wei Tetrahedron, 2010 , vol. 66, # 51 p. 9733 - 9737
  • Route2
    • null|null
      107-06-2
    • null|null
      105-53-3
    • ~84%
    • In-stock
      Diethyl 1,1-cyclopropanedicarboxylate|CS-W022623
      1559-02-0

    References

    • Heiszman, Jozsef; Bitter, Istvan; Harsanyi, Kalman; Toeke,, Laszlo Synthesis, 1987 , # 8 p. 738 - 739
  • Route3
    • null|null
      64648-13-1
    • null|null
      105-53-3
    • ~73%
    • In-stock
      Diethyl 1,1-cyclopropanedicarboxylate|CS-W022623
      1559-02-0

    References

    • Ikeda, Katsuya; Satoh, Hiroshi; Yamamoto, Tamotsu Organic Preparations and Procedures International, 1992 , vol. 24, # 5 p. 548 - 552

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   0.8928
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   4

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