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CS-W001157 4
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(S)​-2,​2'-Dibromo-1,​1'-binaphthalene

  • CAS No. 150024-49-0

  • Cat. No. CS-0086759
  • Molecule weight412.12
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(S)​-2,​2'-Dibromo-1,​1'-binaphthalene|CS-0086759

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General Information

  • CAS No. 150024-49-0
  • Cat. No. CS-0086759
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₁₂Br₂
  • Molecular Weight 412.12
  • Synonym(s) S-(-)-2,2-DIBROMO-1,1'-BINAPHTHYL
  • SMILES BrC1=[C@]([C@]2=C(C=CC=C3)C3=CC=C2Br)C4=C(C=CC=C4)C=C1

Description

(S)-2,2'-Dibromo-1,1'-binaphthalene is a chiral, bench-stable building block featuring two bromine atoms at the 2 and 2' positions of the binaphthyl scaffold. This configuration enables direct incorporation into asymmetric synthesis, where its rigid, sterically defined structure facilitates high enantioselectivity in transition-metal-catalyzed transformations.

Application

(S)-2,2'-Dibromo-1,1'-binaphthalene serves as a chiral scaffold for asymmetric synthesis, enabling stereoselective transformations through its rigid binaphthyl backbone. The bromine substituents facilitate palladium-catalyzed cross-coupling reactions and provide handles for further functionalization. Its bench-stable nature and compatibility with standard synthetic workflows make it a practical building block in the construction of enantioselective catalysts and complex heterocyclic systems.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   7.185
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   1

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