tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate

Name: tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate
Brand: ChemScene
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CAS No. 150008-24-5
Cat. No. CS-0035961
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate|CS-0035961

Structure of 150008-24-5

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General Information

CAS No. 150008-24-5
Cat. No. CS-0035961
Purity ≥97%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₈N₂O₃
Molecular Weight 214.26
Synonym(s) tert-Butyl 4-(hydroxyimino)piperidine-1-carboxylate
SMILES CC(C)(C)OC(=O)N1CCC(=NO)CC1

Description

tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate features a hydroxyimino group at the C4 position of a piperidine scaffold, delivering enhanced stability and controlled reactivity. This bench-stable derivative enables efficient access to functionalized piperidine architectures in medicinal chemistry workflows.

Application

tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate serves as a stable, bench-ready precursor for the synthesis of piperidine-based scaffolds. It enables direct access to functionalized imines and subsequent reduction to secondary amines, facilitating rapid diversification in medicinal chemistry campaigns. The tert-butyl ester group provides excellent stability and ease of removal under mild acidic conditions, while the hydroxyimino functionality offers predictable reactivity in nucleophilic addition and cyclization reactions.

Synthesis

Route1
- 79099-07-3
- ~98%
- In-stock
  
  150008-24-5
References
- Mullen, Philip; Miel, Hugues; Anthony McKervey Tetrahedron Letters, 2010 , vol. 51, # 24 p. 3216 - 3217
Route2
- 79099-07-3
- In-stock
  
  497-19-8
- ~87%
- In-stock
  
  150008-24-5
References
- SmithKline Beecham Corporation Patent: US6077857 A1, 2000 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS02,GHS07,GHS08
Signal Word : Danger	UN#: 1325
Class : 4.1	Packing Group : Ⅱ
Hazard Statements : H228-H302-H317-H319-H341-H351
Precautionary Statements : P210-P240-P264-P270-P280-P330-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 62.13
LogP 1.8475
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Oxime

Building Blocks Skeleton Aliphatic heterocycle compounds Piperidine compounds

Key Words

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tert-Butyl 4-hydroxyiminopiperidine-1-carboxylate

CAS No. 150008-24-5

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