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CS-W001157 4
Total: USD 88.00

(S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline

  • CAS No. 149341-33-3

  • Cat. No. CS-0165868
  • Molecule weight439.49
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline|CS-0165868

Structure of 149341-33-3

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General Information

  • CAS No. 149341-33-3
  • Cat. No. CS-0165868
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₁H₂₂NP
  • Molecular Weight 439.49
  • Synonym(s) (S)-(-)-1-(2-Diphenylphosphino-1-Naphthyl)Isoquinoline (S)-Quinap
  • SMILES C12=CC=NC(C3=C(C=CC4=CC=CC=C34)P(C5=CC=CC=C5)C6=CC=CC=C6)=C1C=CC=C2.[(S) isomer]

Synthesis

  • Route1
    • null|null
      149245-06-7
    • null|null
      829-85-6
    • ~66%
    • (S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline|CS-0165868
      149341-33-3

    References

    • Lim, Chung Woo; Tissot, Olivier; Mattison, Andrew; Hooper, Mark W.; Brown, John M.; Cowley, Andrew R.; Hulmes, David I.; Blacker, A. John Organic Process Research and Development, 2003 , vol. 7, # 3 p. 379 - 384
  • Route2
    • null|null
      1000062-70-3
    • null|null
      829-85-6
    • ~10%
    • (S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline|CS-0165868
      149341-33-3

    References

    • Allan, Kevin M.; Hong, Boram D.; Stoltz, Brian M. Organic and Biomolecular Chemistry, 2009 , vol. 7, # 23 p. 4960 - 4964
  • Route3
    • null|null
      149245-07-8
    • ~85%
    • (S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline|CS-0165868
      149341-33-3

    References

    • Alcock, Nathaniel W.; Brown, John M.; Hulmes, David I. Tetrahedron: Asymmetry, 1993 , vol. 4, # 4 p. 743 - 756

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   12.89
  • LogP   7.4493
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   4

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