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Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride

  • CAS No. 14564-35-3

  • Cat. No. CS-0082011
  • Purity≥98%
  • MDL No.MFCD00009594

*For research and further manufacturing use only, not for direct human use.

Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride|CS-0082011

Structure of 14564-35-3

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General Information

  • CAS No. 14564-35-3
  • Cat. No. CS-0082011
  • Purity ≥98%
  • MDL No. MFCD00009594
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₈H₃₀Cl₂O₂P₂Ru
  • Molecular Weight 752.56
  • Synonym(s) Ruthenium, dicarbonyldichlorobis(triphenylphosphine)-
  • SMILES [C-]#[O+].[C-]#[O+].Cl[Ru](Cl)[P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Description

Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride features a ruthenium(II) center coordinated by two triphenylphosphine ligands and two carbonyl groups, with a chloride counterion. This air-stable complex serves as a versatile precursor in organometallic synthesis, enabling efficient catalytic transformations under mild conditions. The phosphine ligands enhance solubility and stabilize the metal center during reductive processes.

Application

Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride serves as a well-established precatalyst in transition-metal-catalyzed transformations, particularly in carbonylative coupling reactions and C–H functionalization processes. Its bench-stable nature, tolerance to air and moisture under controlled conditions, and predictable reactivity enable reliable formation of active ruthenium species. The ligand set facilitates CO insertion and oxidative addition steps, making it a practical choice for synthesizing ketones, amides, and heterocyclic scaffolds in medicinal chemistry and process development workflows.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   39.8
  • LogP   4.47858
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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