Tris(dibenzoylmethanato)iron(III)

Name: Tris(dibenzoylmethanato)iron(III)
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CAS No. 14405-49-3
Cat. No. CS-0085478
Molecule weight725.60
Purity≥97%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Tris(dibenzoylmethanato)iron(III)|CS-0085478

Structure of 14405-49-3

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General Information

CAS No. 14405-49-3
Cat. No. CS-0085478
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₅H₃₃FeO₆
Molecular Weight 725.60
Synonym(s) Tris(dibenzoylmethanato)iron
SMILES C1(C2=CC=CC=C2)=O[Fe]OC(C3=CC=CC=C3)=C1

Description

Tris(dibenzoylmethanato)iron(III) is a bench-stable, air-tolerant iron(III) complex featuring three dibenzoylmethanato ligands coordinated in a meridional arrangement. This chelated structure enhances solubility in organic solvents and provides robust thermal stability, enabling reliable use in catalytic oxidation reactions and as a precursor for metal-organic frameworks.

Application

Tris(dibenzoylmethanato)iron(III) serves as a stable, bench-accessible iron(III) complex that facilitates Lewis acid-catalyzed transformations in organic synthesis. Its well-defined coordination sphere enables efficient activation of carbonyl groups and promotes C–C bond formation under mild conditions. The ligand framework provides excellent solubility and thermal stability, simplifying purification and reaction monitoring. This reagent functions reliably in standard synthetic workflows requiring controlled metal-mediated catalysis.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P233-P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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Tris(dibenzoylmethanato)iron(III)

CAS No. 14405-49-3

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