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CS-W001157 4
Total: USD 88.00

Phosphonium, cyclopropyltriphenyl-, bromide 1:1

  • CAS No. 14114-05-7

  • Cat. No. CS-0031381
  • Purity≥95%
  • MDL No.MFCD00011872

*For research and further manufacturing use only, not for direct human use.

Phosphonium, cyclopropyltriphenyl-, bromide 1:1|CS-0031381

Structure of 14114-05-7

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General Information

  • CAS No. 14114-05-7
  • Cat. No. CS-0031381
  • Purity ≥95%
  • MDL No. MFCD00011872
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₁H₂₀BrP
  • Molecular Weight 383.26
  • Synonym(s) NSC 110599
  • SMILES C1([P+](C2CC2)(C3=CC=CC=C3)C4=CC=CC=C4)=CC=CC=C1.[Br-]

Description

Used for electrolytic polarization of ZnStudied for potential antitumor activityReactant for synthesis of:Keto halides for sequential azidation and intramolecular Schmidt reactionsCycloporpylidenemethylarylethynynesDipeptides containing azabicyclo[3.1.0]hexaneReactant for hydroalkynylation

Synthesis

  • Route1
    • (3-Bromopropyl)triphenylphosphonium bromide Olopatadine  Impurity|CS-0228817
      3607-17-8
    • ~91%
    • In-stock
      Phosphonium, cyclopropyltriphenyl-, bromide 1:1|CS-0031381
      14114-05-7

    References

    • Maercker, Adalbert; Daub, Volker E. E. Tetrahedron, 1994 , vol. 50, # 8 p. 2439 - 2458
  • Route2
    • null|null
      603-35-0
    • In-stock
      1,3-Dibromopropane|CS-W020641
      109-64-8
    • ~36%
    • In-stock
      Phosphonium, cyclopropyltriphenyl-, bromide 1:1|CS-0031381
      14114-05-7

    References

    • Celebi, Sol; Leyva, Soccoro; Modarelli, David A.; Platz, Matthew S. Journal of the American Chemical Society, 1993 , vol. 115, # 19 p. 8613 - 8620
  • Route3
    • null|null
      603-35-0
    • ~%
    • In-stock
      Phosphonium, cyclopropyltriphenyl-, bromide 1:1|CS-0031381
      14114-05-7

    References

    • Tetrahedron, , vol. 29, p. 1169 - 1171

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   1.1469
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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