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CS-W001157 4
Total: USD 88.00

Chlorocarbonylbis(triphenylphosphine)rhodium(I)

  • CAS No. 13938-94-8

  • Cat. No. CS-0081881
  • Purity≥97%
  • MDL No.MFCD00044273

*For research and further manufacturing use only, not for direct human use.

Chlorocarbonylbis(triphenylphosphine)rhodium(I)|CS-0081881

Structure of 13938-94-8

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General Information

  • CAS No. 13938-94-8
  • Cat. No. CS-0081881
  • Purity ≥97%
  • MDL No. MFCD00044273
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₇H₃₀ClOP₂Rh
  • Molecular Weight 690.93
  • Synonym(s) trans-Bis(triphenylphosphine)rhodium(I) carbonyl chloride
  • SMILES Cl[Rh-]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([C+]=O)[P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

Description

Chlorocarbonylbis(triphenylphosphine)rhodium(I) is a bench-stable, moisture-tolerant catalyst that facilitates efficient carbonylation reactions. This rhodium complex features a coordinatively unsaturated site, enabling rapid insertion of CO and olefins. It integrates seamlessly into homogeneous catalysis workflows, delivering high selectivity in aldehyde synthesis under mild conditions.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302+H312+H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P501

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   6.6441
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   9

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