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CS-W001157 4
Total: USD 88.00

Trimethyl((1-phenylvinyl)oxy)silane

  • CAS No. 13735-81-4

  • Cat. No. CS-0127818
  • Purity≥95%
  • MDL No.MFCD00008582

*For research and further manufacturing use only, not for direct human use.

Trimethyl((1-phenylvinyl)oxy)silane|CS-0127818

Structure of 13735-81-4

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General Information

  • CAS No. 13735-81-4
  • Cat. No. CS-0127818
  • Purity ≥95%
  • MDL No. MFCD00008582
  • Storage -20°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₁H₁₆OSi
  • Molecular Weight 192.33
  • Synonym(s) α-(Trimethylsilyloxy)styrene
  • SMILES C=C(C1=CC=CC=C1)O[Si](C)(C)C

Description

1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:-amino ketones in water via Mannich-type reactioncis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction

Synthesis

  • Route1
    • null|null
      75-77-4
    • In-stock
      Acetophenone|CS-0015982
      98-86-2
    • ~98%
    • In-stock
      Trimethyl((1-phenylvinyl)oxy)silane|CS-0127818
      13735-81-4

    References

    • Lin, Ji-Mao; Liu, Ben-Sheng Synthetic Communications, 1997 , vol. 27, # 5 p. 739 - 749
  • Route2

    References

    • Honda, Mitsunori; Nakajima, Tadashi; Okada, Maiko; Yamaguchi, Keita; Suda, Mitsuhiro; Kunimoto, Ko-Ki; Segi, Masahito Tetrahedron Letters, 2011 , vol. 52, # 29 p. 3740 - 3742
  • Route3
    • null|null
      100-52-7
    • null|null
      18107-18-1
    • ~0%
    • In-stock
      Trimethyl((1-phenylvinyl)oxy)silane|CS-0127818
      13735-81-4
    • null|null
      35449-04-8
    • null|null
      35449-05-9

    References

    • Dias; Brookhart; White Journal of the American Chemical Society, 2001 , vol. 123, # 10 p. 2442 - 2443

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H227-H315-H319-H335
Precautionary Statements : P210-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P403-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   3.5088
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   3

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