methyl 2-hydroxy-4-nitrobenzoate

Name: methyl 2-hydroxy-4-nitrobenzoate
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CAS No. 13684-28-1
Cat. No. CS-0036685
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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methyl 2-hydroxy-4-nitrobenzoate|CS-0036685

Structure of 13684-28-1

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Description

Methyl 2-hydroxy-4-nitrobenzoate features a strategically positioned hydroxyl group and electron-deficient nitro moiety, enabling selective conjugation in synthetic pathways. This bench-stable ester integrates readily into complex molecular architectures under standard conditions.

Application

Methyl 2-hydroxy-4-nitrobenzoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted benzoic acid derivatives and heterocyclic scaffolds. The ortho-hydroxyl and para-nitro groups provide complementary reactivity for sequential functionalization, including palladium-catalyzed coupling reactions and electrophilic substitution. Its bench-stable nature and straightforward purification support reliable use in medicinal chemistry campaigns and process development workflows.

General Information

CAS No. 13684-28-1
Cat. No. CS-0036685
Purity ≥98%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇NO₅
Molecular Weight 197.15
Synonym(s) NSC 165605
SMILES COC(=O)C1=CC=C(C=C1O)[N+](=O)[O-]

Computational Chemistry Data

TPSA 89.67
LogP 1.087
H_Acceptors 5
H_Donors 1
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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methyl 2-hydroxy-4-nitrobenzoate

CAS No. 13684-28-1

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