Zinc(II) 2-ethylhexanoate

Name: Zinc(II) 2-ethylhexanoate
Brand: ChemScene
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CAS No. 136-53-8
Cat. No. CS-0196714
PurityZn ~18%
MDL No.MFCD00053316

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 136-53-8
Cat. No. CS-0196714
Purity Zn ~18%
MDL No. MFCD00053316
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₆H₃₂O₄Zn
Molecular Weight 353.80
Synonym(s) Zincethylhexanoatecainmineralspiritsoffwhiteviscous
SMILES CCCCC(CC)C(=O)O.CCCCC(CC)C(=O)O.[Zn]

Description

Zinc(II) 2-ethylhexanoate is a moisture-tolerant organozinc reagent featuring a bulky alkyl chain that enhances solubility in nonpolar solvents. This formulation enables efficient catalytic performance in polymerization and cross-coupling processes under ambient conditions.

Application

Zinc(II) 2-ethylhexanoate serves as a stable, bench-ready catalyst for esterification and transesterification reactions, enabling efficient coupling of carboxylic acids with alcohols under mild conditions. Its high solubility in organic media and tolerance to diverse functional groups facilitate straightforward purification and scalability. This reagent functions effectively in both stoichiometric and catalytic applications, particularly in the synthesis of polyesters and fine chemical intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS02,GHS08
Signal Word : Danger	UN#: 1993
Class : 3	Packing Group : Ⅲ
Hazard Statements : H226-H304-H340-H350-H361-H372
Precautionary Statements : P210-P233-P240-P241-P242-P243-P260-P264-P270-P280-P331-P370+P378-P405-P501

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Computational Chemistry Data

TPSA 74.6
LogP 4.5723
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 10

Other Classifications

Building Blocks Functional Group Carboxylic Acid

Catalysts and Ligands Catalysts Transition Metal Catalysts Zn Catalysts

Catalysis Non-Precious Metal Catalysis

Catalysis Main-group Elements Zinc

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Key Words

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Zinc(II) 2-ethylhexanoate

CAS No. 136-53-8

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