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CS-W001157 4
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(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

  • CAS No. 135616-36-3

  • Cat. No. CS-W011465
  • Purity≥95%
  • MDL No.MFCD00191801

*For research and further manufacturing use only, not for direct human use.

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine|CS-W011465

Structure of 135616-36-3

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General Information

  • CAS No. 135616-36-3
  • Cat. No. CS-W011465
  • Purity ≥95%
  • MDL No. MFCD00191801
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₆H₅₄N₂O₂
  • Molecular Weight 546.83
  • Synonym(s) 6,6-[(1S,2S)-Cyclohexane-1,2-Diylbis(Iminomethylylidene)]Bis(2,4-Di-Tert-Butylcyclohexa-2,4-Dien-1-One); (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
  • SMILES OC1=C(C(C)(C)C)C=C(C(C)(C)C)C=C1/C=N/[C@@H]2[C@@H](/N=C/C3=C(O)C(C(C)(C)C)=CC(C(C)(C)C)=C3)CCCC2

Description

(S,S)-(+)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsens catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.

Synthesis

  • Route1
    • In-stock
      3,5-Di-tert-butyl-2-hydroxybenzaldehyde|CS-W012904
      37942-07-7
    • null|null
      21436-03-3
    • ~%
    • In-stock
      (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine|CS-W011465
      135616-36-3

    References

    • Helvetica Chimica Acta, , vol. 85, # 10 p. 3301 - 3312

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   65.18
  • LogP   9.137
  • H_Acceptors   4
  • H_Donors   2
  • Rotatable_Bonds   4

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