1-Bromo-4-cyclopropyl-2-methoxybenzene

Name: 1-Bromo-4-cyclopropyl-2-methoxybenzene
Brand: ChemScene
Availability: InStock
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CAS No. 1353855-71-6
Cat. No. CS-0375868
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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1-Bromo-4-cyclopropyl-2-methoxybenzene|CS-0375868

Structure of 1353855-71-6

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General Information

CAS No. 1353855-71-6
Cat. No. CS-0375868
Purity ≥95%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₁BrO
Molecular Weight 227.10
Synonym(s) Benzene, 1-bromo-4-cyclopropyl-2-methoxy-
SMILES COC1=CC(C2CC2)=CC=C1Br

Description

1-Bromo-4-cyclopropyl-2-methoxybenzene features a cyclopropyl group that imparts unique steric and electronic properties, enhancing its utility in cross-coupling reactions. The methoxy substituent stabilizes electron density at the ortho position, while the bromine serves as a reactive handle for palladium-catalyzed transformations. This compound demonstrates robust stability under standard bench conditions, facilitating efficient integration into synthetic sequences requiring precise functional group placement.

Application

1-Bromo-4-cyclopropyl-2-methoxybenzene serves as a versatile aryl halide building block for palladium-catalyzed cross-coupling reactions, enabling efficient access to biaryl scaffolds. The cyclopropyl group enhances metabolic stability, while the methoxy functionality provides orthogonal reactivity and mild directing effects. Bench-stable and compatible with standard Suzuki, Stille, and Negishi protocols, it facilitates streamlined synthesis of complex functionalized aromatics relevant to medicinal chemistry and materials science.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P501

Quality Control

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Computational Chemistry Data

TPSA 9.23
LogP 3.3351
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Building Blocks Skeleton Fatty ring compounds Cyclopropane compounds

Key Words

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1-Bromo-4-cyclopropyl-2-methoxybenzene

CAS No. 1353855-71-6

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