Methyl 4-methylpicolinate

Name: Methyl 4-methylpicolinate
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CAS No. 13509-13-2
Cat. No. CS-0040863
Purity≥97%
MDL No.MFCD09265118

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 13509-13-2

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General Information

CAS No. 13509-13-2
Cat. No. CS-0040863
Purity ≥97%
MDL No. MFCD09265118
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉NO₂
Molecular Weight 151.16
Synonym(s) Methyl 4-methyl-2-picolinate
SMILES O=C(C1=NC=CC(C)=C1)OC

Description

Methyl 4-methylpicolinate is a bench-stable, moisture-tolerant ester featuring a para-methyl-substituted picolinic acid scaffold. This electron-deficient heterocycle integrates readily into synthetic sequences requiring polar, nitrogen-containing building blocks. The methyl ester group enables straightforward derivatization and facilitates purification in chromatographic workflows.

Application

Methyl 4-methylpicolinate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted pyridine derivatives through standard functional group manipulations. Its methyl ester functionality offers enhanced bench stability and facilitates straightforward hydrolysis or coupling reactions. The 4-methyl substituent provides steric and electronic modulation, improving compatibility in palladium-catalyzed cross-coupling processes and aiding in the construction of heterocyclic scaffolds relevant to medicinal chemistry and agrochemical development.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.17662
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 4-methylpicolinate

CAS No. 13509-13-2

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