Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate

Name: Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate
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CAS No. 1350821-95-2
Cat. No. CS-0049066
Molecule weight184.23
Purity≥98%
MDL No.None

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Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate|CS-0049066

Structure of 1350821-95-2

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General Information

CAS No. 1350821-95-2
Cat. No. CS-0049066
Purity ≥98%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₆O₃
Molecular Weight 184.23
Synonym(s) methyl 4-(hydroxymethyl)norbornane-1-carboxylate
SMILES COC(=O)C12CCC(CO)(CC1)C2

Description

Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate features a rigid bicyclic framework with a pendant hydroxymethyl group, offering a stereodefined scaffold for synthetic exploration. The ester functionality enables selective derivatization, while the hydroxymethyl moiety provides a handle for further functionalization under standard conditions. This compound serves as a valuable building block in asymmetric synthesis and medicinal chemistry.

Application

Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate serves as a versatile synthetic building block for strained bicyclic architectures, enabling efficient access to functionalized norbornane derivatives. The pendant hydroxymethyl group offers direct handle for oxidation, protection, or conjugation, while the ester moiety facilitates selective transformations. Its robust bench stability and compatibility with standard coupling and reduction protocols make it ideal for medicinal chemistry campaigns requiring rigid, three-dimensional scaffolds.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 46.53
LogP 1.1022
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Bridge Rings compounds Other bridge ring compounds

Key Words

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Methyl 4-(hydroxymethyl)bicyclo[2.2.1]heptane-1-carboxylate

CAS No. 1350821-95-2

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