Lot numbers can be found on the outside label of a product:
Tetrakis[4-(iodo)phenyl]methane
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CAS No. 134080-67-4
- Cat. No. CS-0169797
- Purity≥97%
- MDL No.MFCD30478578
*For research and further manufacturing use only, not for direct human use.
![Tetrakis[4-(iodo)phenyl]methane|CS-0169797](https://file.chemscene.com/productPIC/CS-0169797.gif)
Structure of 134080-67-4
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General Information
- CAS No. 134080-67-4
- Cat. No. CS-0169797
- Purity ≥97%
- MDL No. MFCD30478578
- Storage RT, protect from light
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₂₅H₁₆I₄
- Molecular Weight 824.01
- Synonym(s) Benzene, 1,1',1'',1'''-methanetetrayltetrakis[4-iodo-
- SMILES IC1=CC=C(C(C2=CC=C(I)C=C2)(C3=CC=C(I)C=C3)C4=CC=C(I)C=C4)C=C1
Description
Tetrakis[4-(iodo)phenyl]methane features four iodophenyl groups attached to a central methane core, enabling efficient coupling in cross-coupling reactions. This sterically crowded architecture enhances stability and facilitates use in Pd-catalyzed transformations, offering reliable access to complex aryl scaffolds under standard conditions.
Application
Tetrakis[4-(iodo)phenyl]methane serves as a versatile tetraaryl building block for palladium-catalyzed cross-coupling reactions, enabling efficient construction of complex polycyclic architectures. Its four iodophenyl groups exhibit high reactivity in Suzuki, Stille, and Negishi couplings, with excellent functional group tolerance and bench stability. The molecule functions as a robust scaffold for the synthesis of conjugated materials and multiaryl scaffolds relevant to organic electronics and medicinal chemistry.
Synthesis
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Route1
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In-stock
630-76-2 - ~59%
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In-stock
134080-67-4
References
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Aujard; Baltaze; Baudin; Cogne; Ferrage; Jullien; Perez; Prevost; Lin Mao Qian; Ruel Journal of the American Chemical Society, 2001 , vol. 123, # 34 p. 8177 - 8188
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Route2
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205384-30-1 - ~27%
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In-stock
134080-67-4
References
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Li, Quan; Rukavishnikov, Aleksey V; Petukhov, Pavel A; Zaikova, Tatiana O; Keana, John F W Organic letters, 2002 , vol. 4, # 21 p. 3631 - 3634
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Route3
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In-stock
22948-06-7 - ~%
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In-stock
134080-67-4
References
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Su, Dan; Menger Tetrahedron Letters, 1997 , vol. 38, # 9 p. 1485 - 1488
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319
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Precautionary Statements : P264-P280-P302+P352-P362+P364
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Quality Control
Computational Chemistry Data
- TPSA 0
- LogP 8.4877
- H_Acceptors 0
- H_Donors 0
- Rotatable_Bonds 4
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Key Words
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