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CS-W001157 4
Total: USD 88.00

Acetylacetonate-1,5-cyclooctadienerhodium(I)

  • CAS No. 12245-39-5

  • Cat. No. CS-0035167
  • Purity≥97%
  • MDL No.MFCD00075046

*For research and further manufacturing use only, not for direct human use.

Acetylacetonate-1,5-cyclooctadienerhodium(I)|CS-0035167

Structure of 12245-39-5

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General Information

  • CAS No. 12245-39-5
  • Cat. No. CS-0035167
  • Purity ≥97%
  • MDL No. MFCD00075046
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₃H₁₉O₂Rh
  • Molecular Weight 310.19
  • Synonym(s) Rhodium (1,5-cyclooctadiene)-2,4-pentanedionate
  • SMILES C[Rh]1(C)OC(C)CC(C)O1.C2=C\CC/C=C\CC/2

Application

Acetylacetonate-1,5-cyclooctadienerhodium(I) serves as a robust, air-stable precatalyst for Rh(I)-mediated C–H activation and conjugate addition reactions. Its well-defined coordination sphere enables selective functionalization of complex substrates under mild conditions, with excellent tolerance to common functional groups. The ligand framework facilitates rapid catalyst turnover in cross-coupling and cyclization processes, making it a practical choice for iterative synthesis in medicinal chemistry and process development workflows.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P260-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   4.9532
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   0

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