Methyl 5,6-dichloropicolinate

Name: Methyl 5,6-dichloropicolinate
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CAS No. 1214375-24-2
Cat. No. CS-0109598
Purity≥97%
MDL No.MFCD14698032

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Type	HazMat Fee
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FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 5,6-dichloropicolinate|CS-0109598

Structure of 1214375-24-2

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General Information

CAS No. 1214375-24-2
Cat. No. CS-0109598
Purity ≥97%
MDL No. MFCD14698032
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅Cl₂NO₂
Molecular Weight 206.03
Synonym(s) 2-Pyridinecarboxylic acid, 5,6-dichloro-, methyl ester
SMILES O=C(C1=NC(Cl)=C(Cl)C=C1)OC

Description

Methyl 5,6-dichloropicolinate is a bench-stable, electron-deficient heterocyclic ester featuring two adjacent chlorine substituents on the pyridine ring. This configuration enhances its reactivity in cross-coupling and nucleophilic substitution processes. The methyl ester group enables straightforward derivatization, while the dichloro substitution pattern provides strong electronic activation for transition metal catalysis.

Application

Methyl 5,6-dichloropicolinate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to substituted pyridine scaffolds. Its dual chloro substituents enhance electrophilicity at the aromatic ring, facilitating nucleophilic aromatic substitution and transition-metal-catalyzed coupling reactions. The ester functionality allows for selective reduction or hydrolysis, supporting downstream derivatization. Bench-stable and compatible with standard purification methods, it functions reliably in multi-step syntheses requiring functional group tolerance and predictable reactivity.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 2.175
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

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Methyl 5,6-dichloropicolinate

CAS No. 1214375-24-2

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