Methyl 6-bromo-4-chloropicolinate

Name: Methyl 6-bromo-4-chloropicolinate
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CAS No. 1206249-92-4
Cat. No. CS-0150751
Purity≥97%
MDL No.MFCD14582022

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Methyl 6-bromo-4-chloropicolinate|CS-0150751

Structure of 1206249-92-4

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General Information

CAS No. 1206249-92-4
Cat. No. CS-0150751
Purity ≥97%
MDL No. MFCD14582022
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrClNO₂
Molecular Weight 250.48
Synonym(s) methyl 6-bromo-4-chloropyridine-2-carboxylate
SMILES COC(=O)C1=NC(=CC(=C1)Cl)Br

Description

Methyl 6-bromo-4-chloropicolinate is a halogenated pyridine derivative featuring strategically positioned bromo and chloro substituents at the 6- and 4-positions, respectively. This electron-deficient heterocycle integrates readily into cross-coupling reactions, serving as a key intermediate in the synthesis of functionalized pharmaceuticals and agrochemicals. The methyl ester group enhances solubility and provides a handle for further derivatization under standard conditions.

Application

Methyl 6-bromo-4-chloropicolinate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling palladium-catalyzed cross-coupling reactions due to its complementary halogenation pattern. The methyl ester group facilitates downstream functionalization, while the ortho-halogen substitution supports selective transformations. Bench-stable and readily purified by crystallization, it functions effectively in standard heterocycle construction and late-stage derivatization workflows.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 2.2841
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 6-bromo-4-chloropicolinate

CAS No. 1206249-92-4

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